激光辐照非晶Fe73.5Cu1Nb3Si13.5B 9微量晶化的穆斯堡尔谱研究

在激光功率为40—160W、扫描速度为10mm/s、激光光斑为20mm照射条件下,用CO ₂激 光辐照非晶Fe_73.5Cu₁Nb₃Si_13.5B_{9< /sub>产生微量晶化.利用透射穆斯堡尔谱 （TMS）技术分析了原始态和晶化后样品的超精细结构.确定了穆斯堡尔谱的基本参数——化 学位移(IS)、四极分裂(QS)、内磁场(Hhf)随激光功率变化的规律.分析表明，CO2关键词： 激光辐照 微量晶化 73.5Cu1Nb3 Si13.5B9')" href="#">非晶Fe73.5Cu1Nb3 Si13.5B9 穆斯堡尔谱}

A study of Mssbauer spectroscopy of microcrystallization of amorphous Fe7 3.5Cu1Nb3Si13.5B9 irradiated b y a CO2-Laser

Microcrystalline phases were produced by laser irradiation on the Fe_{73.5Cu1Nb3Si13.5B9 amorphous ribbon with a power ranging from 40 to 170W,scaning speed 10mm/s,laser beam spot 20mm. Hyperfine structures of the original and crystallized samples were analyzed by transmission Mssbauer spectros copy. We discovered that the basic parameters of the Mssbauer spectra——isome r shift（IS）, quadrupole splitting（QS） and hyperfine magnetic field（Hhf） ch ange with the laser power. Experimental results show that the magnetic moment re organization of Fe73.5Cu1Nb3Si13.5 B9 amorphous phases has take n place and the atom magnetic moment direction maintains a preferred in-plane or ientation, The average hyperfine magnetic field of the amorphous phase is improv ed because of the microcrystalline phase. The crystallized phase was Fe-Si alloy with a DO3 structure, and the area of its spectral lines is about 2% —3.4%. This is caused by the jump of one electron in Fe atom 3d⁶ shell int o Si atom 3p² shell, forming a stability electron group.}