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| 掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁 | |
| 引用本文： | 陈晓波,廖红波,张春林,于春雷,潘伟,胡丽丽,吴正龙.掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁[J].物理学报,2010,59(7):5091-5099. |
| 作者姓名： | 陈晓波 廖红波 张春林 于春雷 潘伟 胡丽丽 吴正龙 |
| 作者单位： | 1. 北京师范大学应用光学北京市重点实验室,北京,100875 2. 中国科学院物理研究所,北京,100190 3. 中国科学院上海高功率激光玻璃研究中心,上海,201800;中国科学院上海光学精密机械研究所,上海,201800 4. 北京大学化学与分子工程学院,北京,100871 5. 中国科学院上海高功率激光玻璃研究中心,上海,201800 |
| 基金项目： | 国家自然科学基金 (批准号:10674019)资助的课题. |
| 摘 要： | 研究了掺铒的纳米相氟氧化物玻璃陶瓷(Er(3):FOV)的红外量子剪裁现象,测量了红外和可见的Er(3):FOV的荧光光谱.结果发现光激发2H11/2能级的4 I13/2→4I15/2荧光跃迁的近似量子剪裁效率已达约186.28%.计算了有关的无辐射弛豫速率、自发辐射速率和能量传递速率,分析了有关的能量传递动力学过程,发现 |
| 关 键 词： | 红外量子剪裁现象 太阳能电池 掺铒的纳米相氟氧化物玻璃陶瓷 |
| 收稿时间： | 2009-10-12 |
Infrared multi-photon quantum cutting of Er-doped nanophase oxyfluoride vitroceramics |
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| Chen Xiao-Bo,Liao Hong-Bo,Zhang Chun-Lin,Yu Chun-Lei,Pan Wei,Hu Li-Li,Wu Zheng-Long.Infrared multi-photon quantum cutting of Er-doped nanophase oxyfluoride vitroceramics[J].Acta Physica Sinica,2010,59(7):5091-5099. | |
| Authors: | Chen Xiao-Bo Liao Hong-Bo Zhang Chun-Lin Yu Chun-Lei Pan Wei Hu Li-Li Wu Zheng-Long |
| Institution: | Key Laboratory of Applied Optics of Beijing, Beijing Normal University, Beijing 100875, China;Key Laboratory of Applied Optics of Beijing, Beijing Normal University, Beijing 100875, China;Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;Shanghai Research Center of High Power Laser Glass, Chinese Academy of Sciences, Shanghai 201800, China;College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;Shanghai Research Center of High Power Laser Glass, Chinese Academy of Sciences, Shanghai 201800, China;Key Laboratory of Applied Optics of Beijing, Beijing Normal University, Beijing 100875, China |
| Abstract: | The article reports the infrared quantum cutting phenomenon of the Er-doped nanophase oxyfluoride vitroceramics (Er(3):FOV). The infrared and visible fluorescence spectra of Er(3):FOV are measured carefully. It is found that the approximate quantum cutting efficiency of the 1543.0 nm 4I13/2→4I15/2 fluorescence, when the 2H11/2 levels are excited, is about 186.28%. The relative nonradiative relaxation rate and spontaneous emission rate and energy transfer rate are calculated. The relative energy transfer dynamics is analyzed. It is found that the {2H11/2→4I9/2, 4I15/2→4I13/2} energy transfer channel, with the rate of 371000 s-1, is the main reason for 2H11/2 energy level to have high quantum cutting efficiency. To our best knowledge, the present article for the first time reports Er(3):FOV to have an effective three-photon infrared quantum cutting excited by visible light and a four-photon infrared quantum cutting excited by near-violet light. |
| Keywords: | infrared quantum cutting solar cell Er-doped nanophase oxyfluoride vitroceramics |
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