影响聚合物离子导体电导率的一些因素

本文研究了极性基团浓度、碱金属盐阳离子和阴离子尺寸对均聚物聚环氧氯丙烷(PECH)和共聚物聚环氧氯丙烷-聚环氧乙烷(PECH-PEO)电导率的影响。对锂盐络合物,极性基团浓度增高,电导率降低。钠盐络合物则正好相反,极性基团浓度越高,电导率越高。碱金属盐阳离子和阴离子尺寸对聚合物离子导体电导率都有明显影响。所研究的聚环氧氯丙烷与三种碱金属盐络合物PECH-MI(M=Li,Na,K)的电导率数据表明,钠盐络合物的电导率最高,锂盐和钾盐络合物的电导率较低。碱金属盐阴离子越大,PECH络合物的电导率越低。此外,还 关键词：

EFFECT OF SOME FACTORS ON CONDUCTIVITIES OF POLYMER IONIC CONDUCTORS

The ionic conductivities of some PECH-and PECH-PEO-alkaline salt complexes have been determined. The effect of some factors such as polar group concentration, cation size and anion size as well as procedure of thin film preparation on conductivity of polymer ionic conductor has been studied. For lithium salt complex the polar group reduces the conductivity, while for sodium salt complex the polar group enhances the conductivity. This phenomenon was explained by a model involving the existence of two kinds of potential well in the polymers. It has been found that the cation size has strong influence on conductivity. For both small Li⁺ and large K⁺ , the conductivity is low but for mediun size Na⁺, the conductivity is high. An ion transport picture in amorphous PECH has been proposed to illustrate this behaviour. In addition, it was shown that the larger the anion size is, the lower the conductivity will be. Finally, the re-sults suggested that the procedure of thin film preparation influenced the film conductivity.