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H_2气氛退火处理对Nb掺杂TiO_2薄膜光电性能的影响
引用本文:张彬,王伟丽,牛巧利,邹贤劭,董军,章勇.H_2气氛退火处理对Nb掺杂TiO_2薄膜光电性能的影响[J].物理学报,2014,63(6):68102-068102.
作者姓名:张彬  王伟丽  牛巧利  邹贤劭  董军  章勇
作者单位:华南师范大学, 光电子材料与技术研究所, 广州 510631
基金项目:广东省科技攻关项目(批准号:2012B010200032);国家自然科学基金(批准号:U1174001);广东省自然科学基金(批准号:S2011010003400);广东省省部产学研项目(批准号:2011A091000033);广州市珠江科技新星项目(批准号:2012J2200023)资助的课题~~
摘    要:采用电子束沉积方法,以钛酸锶(SrTiO3)为衬底制备铌(Nb)掺杂TiO2薄膜并研究后续H2气氛退火处理对其薄膜样品光电性能的影响.结果发现H2气氛热退火处理能有效改善Nb掺杂TiO2薄膜的导电率,最佳电阻率达到5.46×10-3Ω·cm,在可见光范围内的透光率为60%—80%.导电性能的改善与H2气氛退火处理后多晶薄膜的晶粒尺寸变大和大量的氧空位形成及H原子掺杂有关.

关 键 词:Nb掺杂TiO2  电子束沉积  退火  薄膜
收稿时间:2013-11-04

Effects of annealing in H2 atomsphere on optoelectronical properties of Nb-doped TiO2 thin films
Zhang Bin,Wang Wei-Li,Niu Qiao-Li,Zou Xian-Shao,Dong Jun,Zhang Yong.Effects of annealing in H2 atomsphere on optoelectronical properties of Nb-doped TiO2 thin films[J].Acta Physica Sinica,2014,63(6):68102-068102.
Authors:Zhang Bin  Wang Wei-Li  Niu Qiao-Li  Zou Xian-Shao  Dong Jun  Zhang Yong
Abstract:Niobium-doped TiO2 thin films are deposited on strontium titanate substrates by E-beam evaporation deposition. Effects of post-annealing in hydrogen atmosphere on their optoelectrical properties are studied. The results show that the annealing in hydrogen atmosphere can enhance their conductivity values efficiently. The corresponding optium resistivity reaches 5.46×10-3 Ω·cm, and the transmittance values of the thin films are 60%–80%. The improvement in the conductive performance is attributed to the increase of the grain size of polycrystalline thin film, the formation of a lot of oxygen vacancies and H-doping caused by annealing in hydrogen atmosphere.
Keywords: 2')" href="#">Nb-doped TiO2 e-beam evaporation deposition annealing thin film
Keywords:Nb-doped TiO2  e-beam evaporation deposition  annealing  thin film
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