Y型Langmuir-Blodgett膜中分子聚集行为的偶极作用模型

利用经典静电场理论，描述了Y型Langmuir-Blodgett (LB) 膜中棒状分子聚集行为的偶极作用模型，给出了Y型LB膜结构与光谱性质的关系.讨论了Y型膜中分子间距、层间距、分子取向、膜层数等结构参数对分子聚集行为的影响，并在此基础上比较了Y型膜和Z型膜分子聚集行为的异同.理论结果与实验规律符合较好.

The dipole interaction model of the molecular aggregation in Y-type Langmuir-Blodgett film

Based on the classical electrostatic theory, the model of dipole-dipole interaction of rod-like amphiphilic molecules in Y-type Langmuir-Blodgett (LB) film is presented in the paper. The relations between the structure and spectral absorption peak of LB films were obtained by using this model. For Y-type films, the relationship of molecular aggregation state and the structure parameters, i.e. molecular separation distance a, separation d between two adjacent layers, molecular tilt angle θ, and layer number　g, were studied using our model. Then we compared the similarities and differences of aggregation behavior between Y-type and Z-type films. The theoretical results agree well with experimental data.