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Y1-xPrxBa2Cu3O7+δ的红外反射谱
引用本文:叶红娟,冉中原,胡灿明,田是映,刘竞青,黄叶肖,赵忠贤.Y1-xPrxBa2Cu3O7+δ的红外反射谱[J].物理学报,1992,41(8):1345-1352.
作者姓名:叶红娟  冉中原  胡灿明  田是映  刘竞青  黄叶肖  赵忠贤
作者单位:(1)中国科学院红外物理国家重点实验室,上海200083; (2)中国科学院物理研究所,北京100080
摘    要:测量了温度范围为4.2—300K的Y1-xPrxBa2Cu3O7+δ(x=0,0.1,0.2,0.4,0.5,0.61.0)的红外反射谱,发现在低温下Ba模有双模行为,随着x值增大双模强度反转,在YBa2Cu3O7+δ中已被判定为Y模的位于194cm-1的反射峰的位置与Pr的含量无关,即用Pr部份或全部替代Y时此峰不发生频移。建议Pr在Y1-xPrxBa2Cu3O7+δ,中是正4价,Pr的替代使原来可移动的空穴被定域在Pr的周围,使超导电性受到压制。 关键词

关 键 词:高Tc  超导体  红外反射谱  元素替代
收稿时间:9/2/1991 12:00:00 AM

INFRARED REFLECTION SPECTRA OF Y1-xPrxBa2Cu3O7+δ
YE HONG-JUAN,RAN ZHONG-YUAN,HU CAN-MING,TIAN SHI-YING,LIU JING-QING,HUANG YE-XIAO and ZHAO ZHONG-XIAN.INFRARED REFLECTION SPECTRA OF Y1-xPrxBa2Cu3O7+δ[J].Acta Physica Sinica,1992,41(8):1345-1352.
Authors:YE HONG-JUAN  RAN ZHONG-YUAN  HU CAN-MING  TIAN SHI-YING  LIU JING-QING  HUANG YE-XIAO and ZHAO ZHONG-XIAN
Abstract:The infrared refleotion spectra of Y1-xPrxBa2Cu3O7+δ(x = 0,0.1,0.2,0.4,0.5, 0.6, 1.0) are measured in the temprature range of 4.2 to 300K. The measurements show that Ba mode has double mode behavior, the strength of which inverses with increasing x, and that the position of the reflection peak at 194cm-1, which has been identified as Y mode of YBa2Cu3O7+δ, is indenpendent of the density of Pr, i. e, the position of the peak does not change whether the Y is partially or totally substitued by Pr. This indicates that in Y1-xPrxBa2Cu3O7+δ the valence of Pr is tetra-valent. The substitution of Pr make the mobile holes localize around Pr, thereby lead to the suppression of superconductivity.
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