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Interpreting technical evidence from spectral imaging of paintings by Édouard Manet in the Courtauld Gallery
Authors:Silvia Rita Amato  Aviva Burnstock  Maureen Cross  Koen Janssens  Francesca Rosi  Laura Cartechini  Raffaella Fontana  Alice Dal Fovo  Marco Paolantoni  Chiara Grazia  Aldo Romani  Anne Michelin  Christine Andraud  Aurélie Tournié  Joris Dik
Institution:1. Department of Conservation and Technology, The Courtauld Institute of Art, Somerset House, Strand, London, WC2R 0RN UK;2. University of Antwerp, Campus Groenenborger Groenenborgerlaan 171, Antwerp, G.V. 144 2020 Belgium;3. CNR-ISTM, Via Elce di sotto 9, Perugia, 06123 Italy;4. CNR-INO, Largo E. Fermi 6, Florence, 50125 Italy;5. Centre of excellence SMAArt c/o Department of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di sotto 9, Perugia, 06123 Italy;6. Centre de Recherche sur la Conservation, (CRC, USR 3224), Muséum National d'Histoire Naturelle, Ministère de la Culture et de la Communication, CNRS, 36 rue Geoffroy-Saint-Hilaire, CP21, Paris, 75005 France;7. Delft University of Technology, Mekelweg 2, Delft, 2628 the Netherlands
Abstract:The paintings by Édouard Manet in The Courtauld Gallery Déjeuner sur l'herbe (1863–68), Marguerite de Conflans en Toilette de Bal (1870–1880), Banks of the Seine at Argenteuil (1874), and A Bar at the Folies–Bergère (1882) were investigated for the first time using a range of non-invasive in situ analyses. The aims of the study were to investigate the painting techniques and materials used for this group of works and to critically evaluate the technical evidence derived from the integrated use of imaging techniques and portable spectroscopic methods in this context. The paintings were investigated by means of macro X-ray fluorescence (MA-XRF), reflection spectral imaging, portable UV–Vis–NIR spectroscopy, portable Raman spectroscopy, and reflection FTIR. MA-XRF and reflection spectral imaging allowed visualising elements in the compositions that were not visible using traditional methods of technical study. For example, MA-XRF analysis of Déjeuner sur l'herbe revealed elements of the development of the composition that provided new evidence to consider its relationship to other versions of the composition. The study also highlighted questions about the interpretation of elemental distribution maps and spectral images that did not correspond to the reworking visible in X-radiographs. For example, in A Bar at the Folies–Bergère Manet made numerous changes during painting, which were not clearly visualised with any of the techniques used. The research has wider implications for the study of Impressionist paintings, as the results will support technical studies of works by other artists of the period who used similar materials and painting methods.
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