| 莰烯衍生物的1H、13C-NMR及UV研究 |
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| 引用本文： | 毛希安,徐广智,钟平,金进良,李希成.莰烯衍生物的1H、13C-NMR及UV研究[J].波谱学杂志,1988,5(2):117-122. |
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| 作者姓名： | 毛希安 徐广智 钟平 金进良 李希成 |
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| 作者单位： | 1. 中国科学院武汉物理所波谱和原子分子物理开放研究实验室;2. 江西师范大学化学系 |
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| 摘 要： | 本文用1H、13C NMR及UV对六个莰烯衍生物进行了研究,给出了全部13C谱线和部分1H谱线的归属。对13C、1H化学位移进行了关联,获得了近乎直线的13C-1H相关图。结果表明,13C化学位移与UV λmax无必然联系,而与电荷密度密切相关。本文对此进行了讨论。
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| 关 键 词： | 莰烯衍生物 NMR UV 电荷密度效应 |
| 收稿时间： | 1987-04-28 |
13C-NMR AND UV STUDY OF SOME CAMPHENE DERIVATIVES |
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| Mao Xian and Xu Guangzhi.13C-NMR AND UV STUDY OF SOME CAMPHENE DERIVATIVES[J].Chinese Journal of Magnetic Resonance,1988,5(2):117-122. |
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| Authors: | Mao Xian and Xu Guangzhi |
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| Institution: | 1. Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, Academia Sinica;2. Chemistry Department of Jiangxi Normal University |
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| Abstract: | Six camphene derivatives were studied by 1H, 13C NMR and UV spectroscopy. All of the 13C lines and part of the 1H lines were assigned. The results show a linear correlation between 13C and 1H chemical shifts, but a necessary correlation between 13C shifts and UV maximum absorption was not found. In addition electron charge effects dominate 13C chemical shifts. Possible explanation of the electron charge effects on 13C chemical shifts was suggested. |
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| Keywords: | camphene derivatives NMR UV electron charge effects |
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