| 某些五配位磷化合物的31P NMR谱表征 |
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| 引用本文： | 李国炜,刘纶祖.某些五配位磷化合物的31P NMR谱表征[J].波谱学杂志,1995,12(1):87-94. |
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| 作者姓名： | 李国炜 刘纶祖 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | 分析归纳了几种类型五配位磷化合物的31P化学位移规律性.并着重讨论了产主的原因.
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| 关 键 词： | 31P NMR 五配位磷化合物 三角双锥结构 |
| 收稿时间： | 1993-09-17 |
31P NMR SPECTRA CHARACTERIZATION FOR SOME PENTACOORDINATED PHOSPHORUS COMPOUNDS |
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| Li Guowei,Liu Lunzu,Cao Ruzhen, Zhang Shukui and Fu Lanbing.31P NMR SPECTRA CHARACTERIZATION FOR SOME PENTACOORDINATED PHOSPHORUS COMPOUNDS[J].Chinese Journal of Magnetic Resonance,1995,12(1):87-94. |
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| Authors: | Li Guowei Liu Lunzu Cao Ruzhen Zhang Shukui and Fu Lanbing |
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| Institution: | Institute of Elemento-Organic Chemistry, Nankai University. Tianjin 300071 |
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| Abstract: | This paper cited 31P NMR chemical shifts of some pentacoordinated phosphorus compounds, and demonstrated that there are some relations between 31P chemical shifts and chemical structure. The relations are discussed qualitatively, and seem to be dependent on ring strain and π-bond. |
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| Keywords: | ?31)p NMR Pentacoordinated phosphorus compounds Trigonal bipyramid structure |
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