| 核磁共振波谱研究氟化膦配体及其金属配合物的氟谱化学位移 |
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| 引用本文： | 夏之宁,康继军,邓益群,余般梅,石乐明,袁晓燕,黄莺,李志良.核磁共振波谱研究氟化膦配体及其金属配合物的氟谱化学位移[J].波谱学杂志,1998(1). |
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| 作者姓名： | 夏之宁 康继军 邓益群 余般梅 石乐明 袁晓燕 黄莺 李志良 |
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| 作者单位： | 重庆大学应用化学系，湖南大学化学化工系，国防科技大学应用物理系，湖南环保学校基础科学部，中国科技大学化学物理系 |
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| 基金项目： | 国家教委与自然科学基金,机械部跨世纪人才专项基金,日本文部省与科学振兴会资助 |
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| 摘 要： | 研究了氟化膦类系列配位体（ＧＰＦ２：Ｇ＝Ｆ，Ｅｔ２Ｎ，Ｍｅ２Ｎ，Ｃ５Ｈ１０Ｎ，ｎＰｒＯ，ＰｈＯ，ｎｅｏＰｎＯ，２，５ｄｉＭｅＰｈ，ｉｓｏＰｒ，ｅｔｃ．）及其与金属镍（０）铜（Ｉ）钼（０）金（Ｉ）形成的配合物的核磁共振氟谱化学位移的定量分子建模，发现了其中的一些有用规律．
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| 关 键 词： | 核磁共振氟谱，氟化膦配位体，金属配合物，化学位移，分子建模，定量建模 |
ON NUCLEAR MAGNETIC RESONANCE (NMR): Chemical Shifts of\ 19 F NMR for Various Ligands and Metallic Complexes of Phosphorus Fluoride |
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| Xia Zhining a,Kang Jijun ab,Deng Yiqun bd,Yu Banmei c,Shi Leming ae,Yuan Xiaoyan b,\ Huang Ying ab and Li Zhiling abe.ON NUCLEAR MAGNETIC RESONANCE (NMR): Chemical Shifts of\ 19 F NMR for Various Ligands and Metallic Complexes of Phosphorus Fluoride[J].Chinese Journal of Magnetic Resonance,1998(1). |
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| Authors: | Xia Zhining a Kang Jijun ab Deng Yiqun bd Yu Banmei c Shi Leming ae Yuan Xiaoyan b \ Huang Ying ab and Li Zhiling abe |
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| Institution: | Xia Zhining a,Kang Jijun ab,Deng Yiqun bd,Yu Banmei c,Shi Leming ae,Yuan Xiaoyan b,\ Huang Ying ab and Li Zhiling **abe |
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| Abstract: | Systematic investigation was made on Nuclear Magnetic Resonance (NMR). In this article, a series of various ligands of phosphorus fluoride (GPF 2) where G=F(PF 3), Et 2N, Me 2N, C 5H 10 N, nPrO, PhO, neoPnO, 2,5 diMePh, isoPr, etc., and their complexes with several metallic ions and/or atoms such as Ni(0), Cu(I), Mo(0) and Au(I) were examined deeply. Molecular modelling was quantitatively done for\ 19 F NMR chemical shifts. Some useful rules were found. |
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| Keywords: | Chemical shifts of\ 19 F Various ligands of phosphorus fluoride Complexes with metallic ions and atoms Ni(0) Mo(0) Cu(I) and Au(I) Quantitative molecular modelling |
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