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RbMgF3 :Ni2+ 体系晶格局域结构的EPR理论研究
引用本文:冯文林,谌家军.RbMgF3 :Ni2+ 体系晶格局域结构的EPR理论研究[J].波谱学杂志,2006,23(1):95-99.
作者姓名:冯文林  谌家军
作者单位:1.重庆工学院 数理学院应用物理系, 重庆杨家坪 400050; 2.四川大学 材料科学与工程学院, 四川 成都 610064
基金项目:四川省教育厅重点科研基金资助项目(40712003).
摘    要:在考虑掺杂晶体局域畸变的影响后, 建立了联系RbMgF3: Ni2+体系的局域畸变结构与EPR谱间的关系, 并计算了RbMgF3: Ni2+晶体在C3v和D3d对称下的零场分裂参量和g 因数. EPR谱的理论计算值与实验值符合甚好. 

关 键 词:电子顺磁共振(EPR)    晶格局域结构    叠加模型    RbMgF3Ni2+晶体  
文章编号:1000-4556(2006)01-0095-05
收稿时间:2005-05-20
修稿时间:2005-05-202005-07-18

Theoretical Study of EPR Spectrum of Local Lattice Structure in RbMgF3: Ni2+ System
FENG Wen-lin,CHEN Jia-jun.Theoretical Study of EPR Spectrum of Local Lattice Structure in RbMgF3: Ni2+ System[J].Chinese Journal of Magnetic Resonance,2006,23(1):95-99.
Authors:FENG Wen-lin  CHEN Jia-jun
Institution:1.School of Mathematics and Physics, Chongqing Institute of Technology, Chongqing 400050, China; ; 2.College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China
Abstract:Taking account of the effects of local distorted structure of the doped crystal, the relationship between the local distorted structure and the EPR parameters was established for RbMgF_3: Ni 2 system. The zero-field splitting parameter D and the g factors for Ni 2 ions in RbMgF_3 crystals with C_ 3v and D_ 3d symmetry were calculated, and found to agree well with the experimentally measured values.
Keywords:electron paramagnetic resonance  local lattice structure  superposition model  RbMgF_3: Ni 2  crystal
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