| 自由基分子NH2ν2带CO激光磁共振π谱的观测 |
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| 引用本文： | 何矿林,孔繁敖.自由基分子NH2ν2带CO激光磁共振π谱的观测[J].波谱学杂志,1995,12(3):315-318. |
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| 作者姓名： | 何矿林 孔繁敖 |
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| 作者单位： | 1. 中国科学院武汉物理研究所波谱与原子分子物理国家重点实验室, 武汉 430071;2. 中国科学院化学研究所, 北京 100080;3. 华东师范大学物理系, 上海 200062 |
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| 摘 要： | 采用高灵敏度、高分辨率激光磁共振光谱(LMR)方法在6μm谱段测量了自由基分子NH2ν2带的π谱(ΔMJ=0).测量了前人已测过的谱,结果与之较好符合.并观测到了前人没有观测过的新谱,在3支激光谱线下共获得约13支塞曼(Zeeman)跃迁谱线,其中在2支激光谱线下新测得的谱线10支.利用我们已经测得的8]σ谱的新的共振谱线的数值和已取得的激光磁共振谱线的标识方法,可预期得到NH2的一些新的分子参数.
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| 关 键 词： | 自由基NH2 激光磁共振 分子光谱 |
| 收稿时间： | 1994-06-18 |
THE CO LASER MAGNETIC RESONANCE DETECTION OF π TRANSITIONS IN ν2 BAND OF FREE RADICAL NH2 |
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| He Kuanglin,Li Fengyan,Li Jinrui,Liu Zhuan,Kong Fanao,Chen Yangqin.THE CO LASER MAGNETIC RESONANCE DETECTION OF π TRANSITIONS IN ν2 BAND OF FREE RADICAL NH2[J].Chinese Journal of Magnetic Resonance,1995,12(3):315-318. |
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| Authors: | He Kuanglin Li Fengyan Li Jinrui Liu Zhuan Kong Fanao Chen Yangqin |
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| Institution: | 1. State Key Laboretory of Magnetic Resonance and Atomic and Molccular Physics, Wuhan Institute of Physics, The Chinese Academy of Sciences, Wuhan 430071;2. Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080;3. Department of Physics, East China Normal University, Shanghai 200062 |
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| Abstract: | Using the method of CO intracavity laser magnetic resonance (LMR),we have detected the π(ΔMJ=0) transitions of ν2 band of free radical NH2.About 13 Zeeman components in 3 laser lines were detected,among them 3 Zeeman components in 1 laser line agree with the previous reported and 10 Zeeman components in 2 laser lines haven't been reported previously. |
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| Keywords: | Radical NH2 Laser magnetic resonance Molecular spectra |
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