| 二茂铁有机锡衍生物的13C,119Sn NMR研究 |
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| 引用本文： | 张秋禹,徐广智.二茂铁有机锡衍生物的13C,119Sn NMR研究[J].波谱学杂志,1991,8(4):479-486. |
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| 作者姓名： | 张秋禹 徐广智 |
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| 作者单位： | 1. 北京化工学院应用化学系;2. 中国科学院化学所 |
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| 摘 要： | 本文测定了几种二茂铁有机锡衍生物的119Sn,13C NMR谱。对其中几种衍生物的13C NMR谱进行了归属,从而进一步验证了这类化合物的结构。着重讨论了结构如 化合物中取代基X的改变对119Sn化学位移的影响。并对结构如
 类化合物N→Sn异侧配位的问题进行了讨论。
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| 关 键 词： | 有机物二茂铁衍生物 NMR化学位移配位键的转换 |
| 收稿时间： | 1990-05-16 |
STUDIES ON ~(13)C NMR OF ORGANOTINFERROCENCE DERIVATIVES |
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| Zhang Qiuyu,Yan Baozhen and Shi Shujian.STUDIES ON ~(13)C NMR OF ORGANOTINFERROCENCE DERIVATIVES[J].Chinese Journal of Magnetic Resonance,1991,8(4):479-486. |
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| Authors: | Zhang Qiuyu Yan Baozhen and Shi Shujian |
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| Institution: | 1. Beijing Institute of Chemical Technology, 100029;2. Institute of Chemistry the Chinese Academy of Sciences Beijing |
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| Abstract: | The 13C, 119Sn NMR spectra of several organotinferrocence derivatives recently prepared were recorded and 13CNMR spectal peaks assigned, so the structures of this kind of compounds are confirmed further. The influence of variation of X in
compounds with structure of on chemical shift of 119Sn is discussed em-
phatically It is found that change of X has little effect on 119Sn N - Sn transdirect coordination in the compound was also investigated. |
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| Keywords: | Organotinferrocence Denvatives NMR Chemical shift Transdirect coordination |
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