| DVE-MA环化交替共聚物的NMR谱研究 |
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| 引用本文： | 严宝珍.DVE-MA环化交替共聚物的NMR谱研究[J].波谱学杂志,1997,14(4):313-317. |
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| 作者姓名： | 严宝珍 |
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| 作者单位： | 北京化工大学应化系, 北京 100029 |
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| 摘 要： | 环化交替的丁二烯乙醚(DVE)和马来酐(MA)共聚物是具有抗癌作用的生物活性剂,目前研究共聚物的关键是环的大小和构型问题.本文测定了共聚物的1H,13C NMR波谱,并采用2D COSY相关,J-分解等脉冲技术,结合PC-MOD分子能量和偶合常数的计算,与模型化合物相比较,从而对共振谱线进行了分析和归属.讨论了立体化学结构和能量的关系,从而证明了DVE-MA环化交替共聚物是一个包含有五环和六环结构的化合物,其含量之比为0.8:1.
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| 关 键 词： | DVE-MA交替共聚物 PC-MOD计算 2D NMR |
| 收稿时间： | 1997-02-24 |
NMR STUDY OF DVE-MA OF CYCLIC ALTERNATING COPOLYMER |
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| Yan Baozhen.NMR STUDY OF DVE-MA OF CYCLIC ALTERNATING COPOLYMER[J].Chinese Journal of Magnetic Resonance,1997,14(4):313-317. |
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| Authors: | Yan Baozhen |
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| Institution: | Department of Applied Chemistry, Beijing Institute of Chemistry Technollogy, Beijing 100029 |
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| Abstract: | The alternating cyclocopolymer of DVE-MA possesses a wide spectrum of biological activities.including antitumor. Recent research on the structure of a variety of cyclocopolymer has raised a question about the ring structure of this cyclocopolymer. In this paper we report for the first time 2D 1H-1H COSY. 1-13 C COSY and J- resolved spectroscopy to elueidate the 400MHz NMR spectrum of eyclocopolymer of DVE-MA,combined with the PC-MOD calenlation of coupling constant and minimal energy in comparison with model compounds.We discussed the relation of stereochemistry of the copolymer to energy. |
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| Keywords: | Alternating cyclopolymer of DVE-MA PC-MOD calculation 2D NMR |
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