| 山莨菪碱和樟柳碱的NMR研究 |
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| 引用本文： | 王国兴,李丽云,沈联芳,钱保功,黄芬.山莨菪碱和樟柳碱的NMR研究[J].波谱学杂志,1987,4(3):247-252. |
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| 作者姓名： | 王国兴 李丽云 沈联芳 钱保功 黄芬 |
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| 作者单位： | 1. 中国科学院武汉物理研究所;2. 中国科学院生物物理研究所 |
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| 摘 要： | 本文用二维NMR和双共振技术确定了山莨菪碱和樟柳碱的1H和13CNMR谱线归属,并对其结果进行了讨论,推断出山莨菪碱的NCH3主要取平展构型,樟柳碱的NCH3取直立构型。
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| 关 键 词： | 山莨菪碱 樟柳碱 构型 核磁共振 |
| 收稿时间： | 1986-12-29 |
NMR STUDY OF ANISODAMINE AND AN|SODINE |
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| Wang Guoxing Li Liyun Shen Lianfang and Qian Baogong.NMR STUDY OF ANISODAMINE AND AN|SODINE[J].Chinese Journal of Magnetic Resonance,1987,4(3):247-252. |
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| Authors: | Wang Guoxing Li Liyun Shen Lianfang and Qian Baogong |
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| Institution: | 1. Wuhan Institute of Physics, Academia Sinica, Wuhan;2. Institute of Biophysics, Academia Sinica, Beijing |
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| Abstract: | The 1H and 13C NMR signals of anisodamine and anisodine were assigned by two dimensional NMR and double resonance technique.The results are discussed. It was deduced that the NCH3 configuration of anisodine is axial and that of ani-sodamine is equatorial mainly from the 13C NMR chemical shifts. |
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| Keywords: | Anisodamine Anisodine Configuration NMR |
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