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溅射气氛对RF反应磁控溅射制备ZnO薄膜微结构及光致发光特性的影响
引用本文:祐卫国,张勇,李璟,杨峰,CHENG C H,赵勇.溅射气氛对RF反应磁控溅射制备ZnO薄膜微结构及光致发光特性的影响[J].发光学报,2010,31(4):503-508.
作者姓名:祐卫国  张勇  李璟  杨峰  CHENG C H  赵勇
作者单位:1. 西南交通大学超导研究开发中心 材料先进技术教育部重点实验室, 四川 成都 610031; 2. School of Materials Science and Engineering, University of New South Wales, Sydney, NSW 2052, Australia
基金项目:国家自然科学基金,国家重大基础研究项目"973",国家高科技项目"863",高等学校博士点专项科研基金,西南交通大学科研基金 
摘    要:用射频反应磁控溅射法在不同溅射压强和氩氧比下制备了ZnO薄膜,通过X射线衍射(XRD)、扫描电镜(SEM)和光致发光(PL)谱等研究了溅射压强和氩氧比对ZnO薄膜结构和光学性质的影响。测量结果显示,所制备的ZnO薄膜为六角纤锌矿结构,具有沿c轴的择优取向;溅射压强P=0.6Pa,氩氧比Ar/O2=20/5.5sccm时,(002)晶面衍射峰强度和平均晶粒尺寸较大,(O02)XRD峰半峰全宽(FWHM)最小,光致发光紫外峰强度最强。

关 键 词:ZnO薄膜  射频反应磁控溅射  溅射压强  氩氧比  光致发光
收稿时间:2009-09-07
修稿时间:2009-12-24

Effect of Sputtering Atmosphere on the Structure and Optical Properties of ZnO Thin Films by RF Reactive Magnetron Sputtering
YOU Wei-guo,ZHANG Yong,LI Jing,YANG Feng,CHENG C H,ZHAO Yong.Effect of Sputtering Atmosphere on the Structure and Optical Properties of ZnO Thin Films by RF Reactive Magnetron Sputtering[J].Chinese Journal of Luminescence,2010,31(4):503-508.
Authors:YOU Wei-guo  ZHANG Yong  LI Jing  YANG Feng  CHENG C H  ZHAO Yong
Institution:1. Superconductivity R&D Center (SRDC), Southwest Jiaotong University, Chengdu 610031, China,; 2. School of Materials Science and Engineering, University of New South Wales, Sydney, NSW 2052, Australia
Abstract:Thin ZnO films were prepared by RF reactive magnetron sputtering with different sputtering pressure and argon-oxygen ratio.The effect of the sputtering pressure and argon-oxygen ratio on the structure and optical properties of the ZnO films were studied using the X-ray diffraction (XRD), scanning electron microscopy (SEM) and F-7100 photoluminescence (PL) spectroscopy. The results indicated that the thin ZnO films have hexagonal wurtzite single phase structure and a preferred orientation with the c axis perpendicular to the substrates.When the sputtering pressure is 0.6 Pa and the argon-oxygen ratio is Ar/O2=20/5.5 sccm, the (002) plane diffraction peak intensity and the grain size are larger, the FWHM of (002) peak is the smallest,UV photoluminescence peak intensity is the strongest.
Keywords:ZnO films                  RF reactive magnetron sputtering                  sputtering pressure                  argon-oxygen ratio                  photoluminescence
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