| SmP5O14晶体中Sm3+离子的能级和晶场参数 |
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| 引用本文： | 任金生,张思远.SmP5O14晶体中Sm3+离子的能级和晶场参数[J].发光学报,1989,10(3):206-212. |
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| 作者姓名： | 任金生 张思远 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 本文利用光谱方法测定了SmP5O14晶体中Sm3+离子的能级,通过拟合定出晶场参数,利用这些参数所计算的能级和实验能级符合得很好。
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| 关 键 词： | 约化矩阵元 能级 晶场参数 |
| 收稿时间： | 1988-07-21 |
CRYSTAL FIELD PARAMETERS AMD ENERGY LEVELS OF Sm3+ IONS IN SmP5O14 CRYSTAL |
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| Ren Jinsheng,Zhang Siyuan,Wang Qingyuan,Wu Shixue,Dong Xiangming,Bai Yunqi.CRYSTAL FIELD PARAMETERS AMD ENERGY LEVELS OF Sm3+ IONS IN SmP5O14 CRYSTAL[J].Chinese Journal of Luminescence,1989,10(3):206-212. |
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| Authors: | Ren Jinsheng Zhang Siyuan Wang Qingyuan Wu Shixue Dong Xiangming Bai Yunqi |
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| Institution: | Changchun Institute of Applied Chemistry, Academia Sinica |
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| Abstract: | Crystal field parameters for SmP5O14 crystals in the approximation of C2v point group symmetry and the reduced matrix elements(f5a SLJ//Uk//f5 a''S''L''J'') were calculated.The crystal field parameters were fitted and the values of energy levels of Sm3+ ions were calculated. Beside these, calculated values of energy levels were compared with the experimental values which were measured from spectra. |
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