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玉米蛋白质基底上射频磁控溅射法制备ZnO薄膜
引用本文:杨帆,王超,周路,初学峰,闫兴振,王欢,郭亮,高晓红,迟耀丹,杨小天.玉米蛋白质基底上射频磁控溅射法制备ZnO薄膜[J].发光学报,2018,39(10):1431-1438.
作者姓名:杨帆  王超  周路  初学峰  闫兴振  王欢  郭亮  高晓红  迟耀丹  杨小天
作者单位:1. 吉林建筑大学 吉林省建筑电气综合节能重点实验室, 吉林 长春 130118; 2. 吉林建筑大学 电气与计算机学院, 吉林 长春 130118
基金项目:国家自然科学基金(51672103);吉林省科技厅科研项目(20160204069GX,20170101111JC,20170520169JH);吉林省教育厅科研项目(JJKH20170243KJ,JJKH20170241KJ)资助
摘    要:采用射频磁控溅射方法在蛋白质基底上成功地制备了ZnO薄膜,研究了不同靶基距、氩氧比和溅射功率条件对ZnO薄膜性质的影响。结果表明,较小的靶基距有助于ZnO薄膜的c轴择优取向生长。我们还发现,沉积于玉米蛋白质基底的ZnO薄膜存在不同程度的张应力,当Ar/(Ar+O2)为0.7时,ZnO薄膜内的张应力最小。ZnO近带边发光峰有不同程度的红移,我们认为,这是由于晶界势垒和氧空位Vo造成的。随着溅射功率的增大,薄膜生长速率显著加快,晶粒尺寸增大,ZnO的近带边发光峰位逐渐趋向于理论值。

关 键 词:氧化锌薄膜  玉米蛋白膜  磁控溅射  X射线衍射  光致发光谱
收稿时间:2018-01-24

Preparation of ZnO Thin Film on Zein by RF Magnetron Sputtering
YANG Fan,WANG Chao,ZHOU Lu,CHU Xue-feng,YAN Xing-zhen,WANG Huan,GUO Liang,GAO Xiao-hong,CHI Yao-dan,YANG Xiao-tian.Preparation of ZnO Thin Film on Zein by RF Magnetron Sputtering[J].Chinese Journal of Luminescence,2018,39(10):1431-1438.
Authors:YANG Fan  WANG Chao  ZHOU Lu  CHU Xue-feng  YAN Xing-zhen  WANG Huan  GUO Liang  GAO Xiao-hong  CHI Yao-dan  YANG Xiao-tian
Institution:1. Jilin Provincial Key Laboratory of Architectural Electricity & Comprehensive Energy Saving, Jilin Jianzhu University, Changchun 130118, China; 2. School of Electrical Engineering and Computer, Jilin Jianzhu University, Changchun 130118, China
Abstract:ZnO films were deposited on zein by radio frequency(RF) magnetron sputtering technique. We investigated the influences of deposition parameters, such as target-to-substrate distance, Ar/O2 ratio and sputtering power on the properties of ZnO films. The results show that c-axis preferred orientation of ZnO films is obtained at small target-to-substrate distance. We also find that ZnO films deposited on zein is in a state of tensile stress, whereas the film deposited at Ar/(Ar+O2) ratio of 0.7 has the lowest tensile stress. The near-band-edge peaks of ZnO films in photoluminescence spectra show blueshifts. We speculate that the blueshifts are caused by the oxygen vacancy and the electrostatic potentials that exist at the grain boundaries. As the sputtering power increases, the deposition rate and the grain size of ZnO films increase, the near-band-edge peak of ZnO film shifts toward the theoretical value gradually.
Keywords:ZnO films  zein films  magnetron sputtering  X ray diffraction  photoluminescence spectrum
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