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含稀土铕(Ⅲ)配合物光学树脂的制备及光学性能的研究
引用本文:王冬梅,林权,李焕荣,储振兴,符连社,杨柏.含稀土铕(Ⅲ)配合物光学树脂的制备及光学性能的研究[J].发光学报,2000,21(3):261-264.
作者姓名:王冬梅  林权  李焕荣  储振兴  符连社  杨柏
作者单位:1. 吉林大学,化学系,吉林,长春,130023
2. 中国科学院长春应用化学研究所稀土化学与物理开放实验室,吉林,长春,130022
摘    要:报道了将多种稀土铕(Ⅲ)的二元及三元配合物复合于苯乙烯(St)/甲基丙烯酸(HMA)的共聚体系,制备得到具有发光功能的透明光学树脂,对其光学性能进行研究。同时,考察了稀土配合物的含量对聚合物 透明性、发光性能的影响。

关 键 词:光学树脂  稀土配合物  透明性  光学性能
修稿时间:2000-06-18

Preparation and Optical Properties of Transparent Resins Containing Europium Complexes
WANG Dong-mei,LIN Quan,LI Huan-rong,CHU Zhen-xing,FU Lian-she,Yang Bai.Preparation and Optical Properties of Transparent Resins Containing Europium Complexes[J].Chinese Journal of Luminescence,2000,21(3):261-264.
Authors:WANG Dong-mei  LIN Quan  LI Huan-rong  CHU Zhen-xing  FU Lian-she  Yang Bai
Institution:WANG Dong mei 1,LIN Quan 1,LI Huan rong 2,CHU Zhen xing 2,FU Lian she 2,Yang Bai 1*
Abstract:Due to the excellent properties such as lightness,good transparency,impact resistance,processability,and dyeability,optical resins were extending their application as transparent materials replacing inorganic optical materials in wide fields.Rare earth compleses with organic ligands,especially those containing Er\+\{3+\} and Tb 3+ ,often exhibit efficient luminescence such as high luminous intensity,long luminous lifetime and sharp line spectrum. Though rare earth complexes assumed sound luminescence performance,but the stability was different ,as a result,its application was restraint.If rare earth complexes were recombined into a range of suitable cuchion substance,the cushion substance can provied relatively stable environment for the rare earth complexes,which is good to exihbit the luminescent characteristic of the rare earth complexes.Furthermore,the rare earth complexes can offer the cushion substance novel function. According to the principle of molecular design,when introducing rare earth ion into the optical resin,the transparent polymer with luminescent properties could be prepared.In our knowledge,this research has rarely been seen before and is terrifically significantly. In this paper,the rare earth complexes were combined into optical resins,and the resins that possess high transparency and good luminescent properties were obtained,their optical properties were studied.In addition,the relationships between the transparency luminescent properties of the polymer and the content of the components in the copolymer system were investigated.
Keywords:rare  earth complexes  ransparent resins  optical properties
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