Phase transition studies in N(p-n-pentyloxy benzylidene) p-n-decyl aniline |
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Authors: | N V S Rao V G K M Pisipati P V Datta Prasad P R Alapati |
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Institution: | Faculty of Physical Sciences , Nagarjuna University , Nagarjuna Nagar, 522 570, India |
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Abstract: | The temperature dependences of the molar volume, the ultrasonic velocity and the refractive index in N(p-n-pentyloxy benzylidene) p-n-decyl aniline, which exhibits nematic, smectic-A and smectic-B, phases, are presented. The isotropic-nematic and smectic-A-smectic-B phase transitions are found to be of first order while the nematic-smectic-A transition is of second order. The thermal expansion coefficient (a) computed from the molar volume data agrees with a second-order N-SA transition. The computed adiabatic compressibility βad, molar sound velocity (or Rao number Rn ) and molar compressibility (or Wada constant A) are presented. |
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