Helium emission spectra—I. intermediate pressure studies |
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Authors: | Dempsey E Lott RE Glick JA Llewellyn |
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Institution: | Department of Chemistry and the School of Engineering Science, The Florida State University Tallahassee, Florida 32306, U.S.A. |
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Abstract: | The apparent cross sections of the n1P(n = 3,4,5,6) and n1,3D(n = 4,5,6,7) levels have been measured as a function of pressure between 5 and 200 mTorr at 1·5KeV electron impact excitation energy. The 41S apparent cross section was measured under the same conditions to observe secondary electron effects. A detailed analysis is made on the mechanisms of excitation transfer out of the n1P levels in terms of radiative and collision processes. Collisional n1P?nF transfer cross sections are calculated for the n = 4 and n = 5 levels and the results are in agreement with the principle of detailed balance. An analysis of the 61P apparent cross section indicates that collision processes other than n1P?nF become important at n = 6 level in determining collisional transfer out of n1P. Evaluation of n1,3D apparent cross sections show that direct collisional gain and loss become more important as n increases. |
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