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Electrolysis and isoelectric focusing
Authors:CHOI  Y S; LUI  ROGER; YU  XUN
Institution: Department of Mathematics, University of Connecticut Storrs, Connecticut 06268, USA
Department of Mathematical Sciences, Worcester Polytechnic Institute Worcester, Massachusetts 01609, USA
Department of Mathematics, University of Connecticut Storrs, Connecticut 06268, USA
Abstract:This paper consists of two parts. In the first part, the authorsprove the existence of steady-state solutions for a three-specieselectrolyte. The species are subject to both dissociation-associationreactions inside the electrolyte and electrochemical reactionsat the boundary electrodes. This is a common occurrence in electrolysis.In the second part, the authors investigate how to use thismodel to describe isoelectric focusing, which is a common techniqueused to separate large protein molecules. In particular, theisoelectric focusing point for a particular type of proteinmolecule is calculated using formal perturbation analysis.
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