| Crystal Structure and Characterization of 2-N-(2-Hydroxy-benzylidene) Furanmethanoamine Nickel(II) Complex |
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| 作者姓名： | WANG Juna b① XU Honga ZHOU Huaa WEI Pingaa |
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| 作者单位： | WANG Juna，b① XU Honga ZHOU Huaa WEI Pingaa(College of Life Science and Pharmaceutical Engineering，Nanjing University of Technology，Nanjing，Jiangsu 210009，China) b(Department of Forensic Science，Jiangsu Police Institute，Nanjing，Jiangsu 210012，China) |
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| 摘 要： | 1 INTRODUCTION Recently, the low-spin square-planar nickel(II) complexes and high-spin octahedral nickel(II) complexes with Schiff base ligands have received much attention in optical materials1～3]. Some nic- kel(II) complexes are widely used as lubricating oil, rubber industry additives, a fire-resistant additive and fungicide for leather4～7]. Also, their adducts with nitrogen have attracted broad attention due to their potential applications as organic conductors and magnetic mate…
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Crystal Structure and Characterization of 2-N-(2-Hydroxy-benzylidene) Furanmethanoamine Nickel(II) Complex |
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| Abstract: | The Ni(II) complex with ligand 2-N-(2-hydroxy-benzylidene) furanmethano- amine has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C2/c with a = 2.0280(4), b = 0.57700(12), c = 1.7340(4) nm, β = 94.74(3)°, Z = 4, Dc = 1.508 g/cm3, the final R = 0.0434 and wR = 0.1112 for 1843 observed reflections with I > 2σ(I). X-ray analysis revealed that the Ni(II) ion is coordinated by two nitrogen atoms of Schiff base and two oxygen atoms of salicylaldehyde in the equatorial plane, and the coordination geometry can be described as a square. |
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| Keywords: | nickel(II) complex salicylaldehyde crystal structure furfuryl amine Schiff base |
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