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Preparation,characterization and morphological study of poly(<Emphasis Type="Italic">m</Emphasis>-toluidine-<Emphasis Type="Italic">co</Emphasis>-<Emphasis Type="Italic">m</Emphasis>-aminoacetophenone) conductive copolymer
Authors:P S Vijayanand  J Vivekanandan  A Jeeva  R Arun Prasath
Abstract:A new series of copolymers of poly(m-toluidine-co-m-aminoacetophenone) were synthesized by the chemical oxidative method in acid medium. The copolymers were characterized by UV–Vis and FTIR spectroscopy. X-ray diffraction analysis revealed the partial crystalline nature of copolymer. The morphological study by SEM analysis indicated that the surface of the copolymer had the granular structure of agglomerated morphology with average particle size of 200 nm. The conductivity of the copolymers ranged from 2 × 10–4 to 3.3 × 10–8 S/cm and the conductivity decreased with the increase of comonomer concentration. The resultant copolymers showed an enhanced solubility and an improved processability when compared with pure polyaniline.
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