|
|||||
|
|
| 醋酸锰作用下二烯丙基叔胺与[60]富勒烯的自由基环加成反应 | |
| 引用本文： | 邹远林,张丹维,刘颖,罗政,吴世晖,高翔. 醋酸锰作用下二烯丙基叔胺与[60]富勒烯的自由基环加成反应[J]. 有机化学, 2004, 24(12): 1614-1618 |
| 作者姓名： | 邹远林 张丹维 刘颖 罗政 吴世晖 高翔 |
| 作者单位： | 复旦大学化学系,上海,200433 |
| 摘 要： | 二烯丙基叔胺与[60]富勒烯在醋酸锰作用下发生自由基环加成反应,生成[60]富勒烯并吡咯烷衍生物.醋酸锰的用量和反应温度等因素对反应有一定影响.反应可能先由Mn(Ⅲ)与烯丙胺经单电子氧化产生自由基,再与[60]富勒烯加成并进一步环化.研究中得到的各产物的结构均通过波谱学方法表征. |
| 关 键 词： | 醋酸锰 [60]富勒烯 二烯丙基胺 自由基环加成 |
| 修稿时间： | 2004-05-26 |
Manganese(Ⅲ) Acetate Based Radical Cycloaddition of Tertiary Diallylamines with [60] fullerene |
|
| ZOU,Yuan-Lin ZHANG,Dan-Wei LIU,Ying LUO,Zheng WU,Shi-Hui GAO,Xiang. Manganese(Ⅲ) Acetate Based Radical Cycloaddition of Tertiary Diallylamines with [60] fullerene[J]. Chinese Journal of Organic Chemistry, 2004, 24(12): 1614-1618 | |
| Authors: | ZOU Yuan-Lin ZHANG Dan-Wei LIU Ying LUO Zheng WU Shi-Hui GAO Xiang |
| Abstract: | The reaction of [60]fullerene with tertiary diallylamines in the presence of manganese(III) acetate dihydrate afforded [60]fulleropyrrolidine derivatives. The molar ratio of reagents and reaction temperature had somehow effects on the reaction. A possible mechanism of radical cycloaddition onto [60]fullerene initiated by one-electron oxidation of Mn(III) and diallylamines was proposed. The [60]fulleropyrrolidine derivatives prepared from the reactions were characterized by means of spectroscopic techniques. |
| Keywords: | manganese(III) acetate [60]fullerene diallylamine radical cycloaddition |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |