| 铜(Ⅰ)配位聚合物[Cu3Hpt3]n的水热合成、晶体结构及荧光光谱 |
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| 引用本文： | 张俊珺,阳年发,张春华,李碧辉.铜(Ⅰ)配位聚合物[Cu3Hpt3]n的水热合成、晶体结构及荧光光谱[J].无机化学学报,2010,26(3):533-536. |
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| 作者姓名： | 张俊珺 阳年发 张春华 李碧辉 |
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| 作者单位： | 湘潭大学化学化工学院，环境友好化学与应用省部共建教育部重点实验室，湘潭 411105; 衡阳师范学院化学与材料科学系，衡阳 421008,湘潭大学化学化工学院，环境友好化学与应用省部共建教育部重点实验室，湘潭 411105,衡阳师范学院化学与材料科学系，衡阳 421008,湘潭大学化学化工学院，环境友好化学与应用省部共建教育部重点实验室，湘潭 411105 |
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| 摘 要： | Three-dimensional framework copper(Ⅰ) coordination polymer with cuprous chloride, and 3-(pyridin-2-yl)-1,2,4-triazole, has been hydrothermally synthesized. Crystal data for this complex: Monoclinic, space group P21/n, a=1.203 3(2) nm, b=1.289 1(3) nm, c=1.582 3(3) nm, V=2.338(8) nm3, Dc=1.779 g·cm-3, Z=4, F(000)=1 248. GooF =1.060, R1=0.026 6, wR2=0.064 0. The asymmetric structural unit contains three copper atoms and three ligands. Copper ion is coordinated with four nitrogen atoms, forming a distorted tetrahedron. The result of fluorescence spectrum analysis shows that the title complex at room temperature exhibits an intense photoluminescence with maximum emission at 414 nm. CCDC: 759692.
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| 关 键 词： | 铜(Ⅰ)配合物 水热合成 晶体结构 荧光光谱 |
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