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Spouge's Conjecture on Complete and Instantaneous Gelation
Authors:Jeon  Intae
Affiliation:(1) Department of Mathematics, Ohio State University, Columbus, Ohio, 43210
Abstract:
We investigate the stochastic counterpart of the Smoluchowski coagulation equation, namely the Marcus–Lushnikov coagulation model. It is believed that for a broad class of kernels, all particles are swept into one huge cluster in an arbitrarily small time, which is known as a complete and instantaneous gelation phenomenon. Indeed, Spouge (also Domilovskii et al. for a special case) conjectured that K(i, j)=(ij)agr, agr>1, are such kernels. In this paper, we extend the above conjecture and prove rigorously that if there is a function psgr(i, j), increasing in both i and j such that suminfinj=1 1/(jpsgr(i, j))<infin for all i, and K(i, j)geijpsgr(i, j) for all i, j, then complete and instantaneous gelation occurs. Evidently, this implies that any kernels K(i, j)geij(log(i+1)log(j+1))agr, agr>1, exhibit complete instantaneous gelation. Also, we conjuncture the existence of a critical (or metastable) sol state: if limi+jrarrinfinij/K(i, j)=0 and suminfini, j=1 1/K(i, j)=infin, then gelation time Tg satisfies 0<Tg<infin. Moreover, the gelation is complete after Tg.
Keywords:Marcus–  Lushnikov process  Smoluchowski coagulation equation  gelation  complete and instantaneous gelation  sol–  gel interaction
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