Spouge's Conjecture on Complete and Instantaneous Gelation |
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Authors: | Jeon Intae |
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Affiliation: | (1) Department of Mathematics, Ohio State University, Columbus, Ohio, 43210 |
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Abstract: | ![]() We investigate the stochastic counterpart of the Smoluchowski coagulation equation, namely the Marcus–Lushnikov coagulation model. It is believed that for a broad class of kernels, all particles are swept into one huge cluster in an arbitrarily small time, which is known as a complete and instantaneous gelation phenomenon. Indeed, Spouge (also Domilovskii et al. for a special case) conjectured that K(i, j)=(ij) , >1, are such kernels. In this paper, we extend the above conjecture and prove rigorously that if there is a function (i, j), increasing in both i and j such that ![sum](/content/k63v8u0775820122/xxlarge8721.gif) j=1 1/(j (i, j))< for all i, and K(i, j) ij (i, j) for all i, j, then complete and instantaneous gelation occurs. Evidently, this implies that any kernels K(i, j) ij(log(i+1)log(j+1)) , >1, exhibit complete instantaneous gelation. Also, we conjuncture the existence of a critical (or metastable) sol state: if limi+j![rarr](/content/k63v8u0775820122/xxlarge8594.gif) ij/K(i, j)=0 and ![sum](/content/k63v8u0775820122/xxlarge8721.gif) i, j=1 1/K(i, j)= , then gelation time Tg satisfies 0<Tg< . Moreover, the gelation is complete after Tg. |
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Keywords: | Marcus– Lushnikov process Smoluchowski coagulation equation gelation complete and instantaneous gelation sol– gel interaction |
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