Extraction-photometric determination of vanadium(V) with N-hydroxy-N-m-tolyl-N′-(2-methyl-5-chloro)phenyl-p-toluamidine hydrochloride in the presence of acetic,monochloroacetic, and phenylacetic acids |
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Authors: | KS Patel KK Deb RK Mishra |
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Institution: | Department of Chemistry, Ravishankar University, Kaipur-492002 (M.P., India |
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Abstract: | N-Hydroxy-N-m-tolyl-N′-(2-methyl-5-chloro)phenyl-p-toluamidine hydrochloride (HTMCPTH), a monobasic and bidentate chelating agent which reacts with vanadium(V) in carboxylic acid media to develop a blue-violet complex, has been employed as a highly selective reagent for extraction and direct photometric determination of the metal. Solvent extraction experiments indicate that from aqueous acetic acid (1.0–10.0 M), monochloroacetic acid (0.1–10.0 M), and phenylacetic acid (at pH 0.5–6.0) vanadium(V) is quantitatively extracted into chloroform. Almost all common ions including Fe3+, Cu2+, Ni2+, Co2+, Mn2+, Cr3+, Ti4+, Zr4+, and Mo6+ do not interfere with the proposed method. The procedure has been utilized for accurate determination of vanadium in standard steels. |
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