Oxidative addition of (PhSe)2 and (FcSe)2 to zerovalent palladium and platinum trialkylphosphine complexes (Fc = ferrocenyl, [Fe(η-C5H5)(η-C5H4)]) |
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| Authors: | Christopher P. Morley Christopher A. Webster |
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| Affiliation: | a Department of Chemistry, University of Wales, Swansea, Singleton Park, Swansea, SA2 8PP, UK
b Dipartimento di Chimica, Universitá degli Studi di Firenze, Via della Lastruccia 3, 50019 Firenze, Italy |
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| Abstract: | Room temperature reaction of [Pd2(dba)3]/PR3 or [Pt(C2H4)(PR3)2] (dba = dibenzylideneacetone; R = Et, Bu) with the diselenides (R′Se)2 (R′ = Ph, Fc) yielded the oxidative addition products trans-[M(SeR′)2(PR3)2] (M = Pd, Pt). These have been characterised by multinuclear NMR and UV-Vis spectroscopy, mass spectrometry, and, in the cases of trans-[Pt(SePh)2(PR3)2] (R = Et, Bu) and trans-[Pt(SeFc)2(PBu3)2], also by X-ray crystallography. |
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| Keywords: | Ferrocene Selenium Palladium Platinum |
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