Novel boracycles from 2-amino-2-methylpropan-1-ol and borane methyl sulfide: Synthesis and X-ray crystal structures期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Novel boracycles from 2-amino-2-methylpropan-1-ol and borane methyl sulfide: Synthesis and X-ray crystal structures

Authors:	Ofir Baum Morris Srebnik

Affiliation:	^a Department of Natural Products and Medicinal Chemistry, School of Pharmacy, POB 12065, Hebrew University in Jerusalem, 91120, Israel ^b School of Chemistry, Sackler Faculty of Exact Science, Tel-Aviv University, Ramat-Aviv, Israel

Abstract:	On reacting the simple 1,2-amino alcohol: 2-amino-2-methylpropan-1-ol, with borane methyl sulfide (BMS), the expected five member oxazaborolidine ring is not obtained. Instead, two polycyclic structures with trigonal boron atoms 6 and 7 were obtained, and their structure were determined by X-ray crystallography. Compound 6 was obtained in 39% yield and compound 7 was obtained in 7% yield.

Keywords:	Boranes 0" alt=" radical dot" src=" http://cdn.els-cdn.com/sd/entities/rad" class=" glyphImg" >methyl sulfide Oxazaborolidine Crystal structure
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