A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone |
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| Institution: | 1. Jiangsu Police Institute, Nanjing 210031, P. R. China;2. Nanjing Institute of Technology, Nanjing 211167, P. R. China;3. College of Pharmaceutics, Jinhua Polytechnic, Jinhua 321007, P. R. China |
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| Abstract: | A simple rhodium-catalyzed addition reaction of aldehydes with arylboronic acids in aqueous γ-valerolactone provides the corresponding benzylic alcohols in moderate to good yields. Other organoboron reagents (boronic esters, aryl-trifluoroborates, etc.) also showed good compatibilities, albeit with relatively lower yields. |
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| Keywords: | aldehydes arylboronic acids benzylic alcohols rhodium catalysis addition reaction γ-valerolactone green solvent |
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