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As low as reasonably achievable catalyst loadings in the cross metathesis of olefins with ethyl acrylate
Authors:Mudassar AbbasChristian Slugovc
Affiliation:Graz University of Technology, Institute for Chemistry and Technology of Materials, Stremayrgasse 9, A 8010 Graz, Austria
Abstract:A series of ruthenium catalysts for olefin metathesis have been screened in the cross metathesis of 1,9-decadiene with ethyl acrylate. Under optimized reaction conditions a catalyst loading of only 100 ppm in respect to double bonds was sufficient for complete conversion of the diene.
Keywords:Olefin metathesis   Cross metathesis   Ruthenium   Acrylates
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