Reversible repositioning of zinc atoms within single crystals of a zinc polycarboxylate with an open-framework structure |
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| Authors: | Hanson Kenneth Calin Nathalie Bugaris Daniel Scancella Michael Sevov Slavi C |
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| Affiliation: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA. |
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| Abstract: | ![]()
Upon dehydration at 220 degrees C under vacuum, an open-framework zinc tetrahydrofuran-2,3,4,5-tetracarboxylate undergoes reversible single crystal to single crystal conversion by some of the zinc atoms moving to different positions that are 3 A away. The reverse process occurs at room temperature by exposing dehydrated crystals to air. |
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