| 氧和正丁基锂引发的阴离子活性聚合物的反应 |
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| 引用本文： | 胡顺民. 氧和正丁基锂引发的阴离子活性聚合物的反应[J]. 合成化学, 2001, 9(3): 253-255,258 |
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| 作者姓名： | 胡顺民 |
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| 作者单位： | 燕山石化公司合成橡胶厂研究所,北京,102503 |
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| 摘 要： | 对氧和正丁基锂引发的阴离子活性聚合物反应的研究发展,反应产物中有基础分子量两倍的大分子物,而且大分子产物的含量与正丁基锂用量成正向关系,提出了可能的反应机理。
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| 关 键 词： | 正丁基锂 阴离子聚合反应 氧 大分子 反应机理 |
| 文章编号： | 1005-1511(2001)03-253-03 |
The Reaction of Oxygen and Living Polymer with n-BuLi as Initiator |
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| HU Shun min. The Reaction of Oxygen and Living Polymer with n-BuLi as Initiator[J]. Chinese Journal of Synthetic Chemistry, 2001, 9(3): 253-255,258 |
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| Authors: | HU Shun min |
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| Abstract: | The reaction of oxygen and living polymer initiated by [WT5BX]n BuLi was studied. It was found that there was a number of macromolecular polymer in products and the content of the polymer increased with increasing the quantity of ]n BuLi. A possible mechanism was proposed. |
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| Keywords: | n BuLi anionic polymerization O 2 macromolcular |
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