On the protonation of dibenzo-18-crown-6 |
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| Authors: | Emanuel Makrlík Petr Vaňura Jan Budka |
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| Institution: | (1) Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic;(2) Institute of Chemical Technology, Prague, Czech Republic |
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| Abstract: | Abstract The stability constant of the dibenzo-18-crown-6·H3O+ cationic complex species dissolved in nitrobenzene saturated with water has been determined from extraction experiments in
the two-phase water–nitrobenzene system and from γ-activity measurements. Various structures of protonated dibenzo-18-crown-6 are discussed.
Graphical abstract
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| Keywords: | Crown ethers Macrocycles Protonation Complex structure |
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