| 配合物Cu(3，5-DMBA)2(phen)的合成、晶体结构及电化学性质 |
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| 引用本文： | 李昶红,何晓梅,杨颖群,李 薇.配合物Cu(3，5-DMBA)2(phen)的合成、晶体结构及电化学性质[J].无机化学学报,2007,23(8):1449-1452. |
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| 作者姓名： | 李昶红 何晓梅 杨颖群 李 薇 |
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| 作者单位： | 1. 湖南工学院化学化工系,衡阳,421002
2. 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省教育厅资助项目;衡阳师范学院青年骨干基金 |
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| 摘 要： | A copper(Ⅱ) complex Cu(3，5-DMBA)2(phen) has been synthesized by self-assembly of 3，5-dimethylbenzoic acid， 1，10-phenanthroline and copper perchlorate. Crystal data for this complex: Monoclinic， space group C2/c with a=2.348 3(5) nm， b=0.984 4(2) nm， c=1.138 4(2) nm， β=103.02(3)°， V=2.563 9(9) nm3， Dc=1.404 g·cm-3， Z=4， F(000)=1 124， final GooF=1.051， R1=0.035 0， wR2=0.099 8. The crystal structure shows that the copper atom is coordinated with two oxygen atoms from two 3，5-dimethylbenzoic acids and two nitrogen atoms from the 1，10-phenanthroline， forming a square-planar structure. The result of the cyclic voltametric behavior analysis shows that the electron transfer in electrode reaction is quasi-reversible. CCDC: 650387.
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| 关 键 词： | 铜(Ⅱ)配合物 晶体结构 电化学性质 |
| 文章编号： | 1001-4861（2007）08-1449-04 |
| 修稿时间： | 2007-02-262007-05-22 |
Synthesis, Crystal Structure and Electrochemical Properties of Complex Cu(3,5-DMBA)2(phen) |
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| LI Chang-Hong,HE Xiao-Mei,YANG Ying-Qun and LI Wei.Synthesis, Crystal Structure and Electrochemical Properties of Complex Cu(3,5-DMBA)2(phen)[J].Chinese Journal of Inorganic Chemistry,2007,23(8):1449-1452. |
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| Authors: | LI Chang-Hong HE Xiao-Mei YANG Ying-Qun and LI Wei |
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| Institution: | 1Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002;2.Department of Chemistry and materials Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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