Abstract: | X-ray structural studies on the changes in oriented polyethylene fibers during torsion at large and small angles showed that the crystallites undergo shear deformation, and the angle x between the axes of the macromolecules and the upper (lower) faces of the crystallites deviates appreciably from a right angle. As a result of torsion of the fibers, an axial texture of the fibrill is formed, inside which the crystallites are skewed, while the c axes of the crystallites are inclined to the texture axis. The nature of the more specific changes in the structure depends on the ratio between the temperatures of the preliminary orientational drawing of the samples, and the subsequent torsion.The V. I. Lenin Tadzhik State University, Dushanbe, Institute of Macromolecular Compounds, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, No. 1, pp. 160–162, January–February, 1974. |