Nickel catalysis for hydrogenation of <Emphasis Type="Italic">p</Emphasis>-dinitrobenzene to <Emphasis Type="Italic">p</Emphasis>-phenylenediamine |
| |
| Authors: | E V Shuvalova O A Kirichenko L M Kustov |
| |
| Institution: | 1.N. D. Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russian Federation;2.Department of Chemistry,M. V. Lomonosov Moscow State University,Moscow,Russian Federation |
| |
| Abstract: | The activity of supported nickel catalysts (5–20% Ni) in the hydrogenation of p-dinitrobenzene to p-phenylenediamine was investigated. The catalysts were obtained by ureainduced precipitation. Activated carbon, alumina, titania, and silica gel were evaluated as supports. The most active catalysts, 5%Ni/TiO2 and 20%Ni/SiO2, provided 50–54% yields of p-phenylenediamine at complete dinitrobenzene conversion. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
