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The first one-pot synthesis of alkoxycyclopropanes via cyclometalation of styrene with ClnAlEt3−n and RCO2R′ mediated by Cp2ZrCl2
Authors:Usein M. Dzhemilev  Leila O. Khafizova  Rinat R. Gubaidullin  Leonard M. Khalilov  Askhat G. Ibragimov
Affiliation:Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 Prospekt Oktyabrya, Ufa, 450075, Russia
Abstract:The one-pot cyclopropanation of styrene using ClnAlEt3−n (Et2AlCl, EtAlCl2, AlCl3) and carboxylic esters in the presence of Cp2ZrCl2 as catalyst gives rise to alkoxycyclopropanes.
Keywords:Alkoxycyclopropanes   Styrene   Alkyl carboxylates   Zr complexes   Homogeneous catalysis   Alkylhaloalanes   Aluminum chloride
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