Estimation of the effective charges in phosphoryl compounds on the basis of the orbital electronegativity |
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| Authors: | O A Raevskii V E Bel'skii V V Zverev |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions A linear relationship between the charges on the phosphorus and oxygen atoms of the phosphoryl group, calculated on the basis of the orbital electronegativities, and the sum of the induction constants of the substituents at the phosphorus atom was found for compounds of the R3PO type.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2491–2494, November, 1973. |
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