Synthesis and photophysical properties of electron-rich perylenediimide-fullerene dyad |
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| Authors: | Shibano Yuki Umeyama Tomokazu Matano Yoshihiro Tkachenko Nikolai V Lemmetyinen Helge Imahori Hiroshi |
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| Affiliation: | Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | An electron-rich perylenediimide-C60 dyad has been prepared to explore a new type of donor-acceptor system. Time-resolved absorption measurements in benzonitrile revealed unambiguous evidence for the formation of a charge-separated state consisting of perylene diimide radical cation and C60 radical anion via photoinduced electron transfer, showing a new class of artificial photosynthetic models in terms of charge separation. |
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