Ammonia chemical ionization mass spectrometry of alcohols: Structural,stereochemical, molecular-size and temperature effects |
| |
Authors: | Fazil O Gülaar Franois Mermound F Johann Winkler Armand Vuchs |
| |
Institution: | Fazil O. Gülaçar,François Mermound,F. Johann Winkler,Armand Vuchs |
| |
Abstract: | Ammonia chemical ionization (CI) mass spectra of various open-chain, cyclic and unsaturated C5- to C10-alcohols were obtained at source temperatures ranging from 60° to 250°C. The reactivity of the ammonia adduct ion MNH and its fragmentation channels are characteristic for substrate structure. Although strongly temperature-dependent, the spectra give nevertheless information on the OH-group environment as well as on the C-skeleton at any source temperature. Primary, secondary and tertiary alcohols as well as allylic and simple olefinic alcohols can be distinguished by their spectra, which show ammonium adduct ions MNH4]+, adduct dehydrogenation ions MNH4-H2], ammonium substitution ions MNH4-H2O]+ and M-OH]+-ions as the main characteristic peaks. Moreover, konfigurational assignments of stereoisomeric alcohols are possible for larger substrate-size and source-temperature ranges than with isobutane CI mass spectrometry. Homologous M NH-ions show molecular-size control of fragmentation and linear MNH-ions are less stable than branched isomers due to incomplete energy randomization. |
| |
Keywords: | |
|
|