Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ ME Multiple Bonds |
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| Authors: | Florian Hupp Dr Mengtao Ma Franziska Kroll Dr J Oscar C Jimenez‐Halla Dr Rian D Dewhurst Dr Krzysztof Radacki Dr Andreas Stasch Prof?Dr Cameron Jones Prof?Dr Holger Braunschweig |
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| Institution: | 1. Julius‐Maximilians‐Universit?t Würzburg, Am Hubland, 97074 Würzburg (Germany);2. School of Chemistry, Monash University, Melbourne, Victoria, 3800 (Australia);3. Department of Chemistry (DCNE), University of Guanajuato, Noria Alta s/n, 36050 Guanajuato (Mexico) |
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| Abstract: | We present the isolation of the first mononuclear dihalogermylene, and mono‐ and dinuclear stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group 14 centers. Additionally, removal of the halide substituents from the Ge/Sn atom was successfully performed in two ways, halide abstraction and reduction, leading to a variety of unusual structural motifs. |
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| Keywords: | cluster germanium platinum pyramidalization tin |
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