Development of a Halide‐Free Aluminium‐Based Catalyst for the Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide |
| |
| Authors: | Dr. Jose A. Castro‐Osma Prof. Michael North Dr. Xiao Wu |
| |
| Affiliation: | Green Chemistry Centre of Excellence, Department of Chemistry, The University of York, York, YO10 5DD (UK) |
| |
| Abstract: | ![]()
Kinetic studies of the synthesis of glycerol carbonate from glycidol and carbon dioxide have been carried out. These showed that under suitable reaction conditions, bimetallic aluminium(salen) complex 4 is able to catalyse the conversion of epoxides into the corresponding cyclic carbonates without the need for a co‐catalyst. |
| |
| Keywords: | aluminium carbon dioxide catalysts cyclic carbonate epoxide |
|
