Pd nanoparticles on boron doped graphene catalyst for electrochemical detection of hydrogen peroxide prepared by electroless deposition methodEI北大核心CSCD |
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作者姓名: | 胡娅琪 张博 姚琳 秦蓓 |
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作者单位: | 1.西安医学院药学院710021;2.西安医学院药物研究所710021; |
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基金项目: | 陕西省教育厅服务地方专项基金(19JC035);陕西省教育厅专项科研计划(20JK0892);陕西省重点研发计划项目(2017SF-345);西安医学院博士科研启动基金(2017DOC07)资助。 |
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摘 要: | Taking advantage of large conjugated structure and reductivity of boron-doped graphenethe palladium nanoparticles/boron-doped graphene catalyst was prepared by electroless deposition method using boron-doped graphene as reductant and stabilizer. The average size of palladium nanoparticles highly dispersed on the surface of boron-doped graphene was about 6.5 nm. The electrochemical sensor was prepared by modifying the as-formed catalyst on the surface of glassy carbon electrode. The obtained electrochemical sensor exhibited an excellent electrochemical catalytic activity for H2 O2 . It exhibited high sensitivity with the detection limit as low as 830 nmol/L and good linearity in the range of 2.5-300 μµmol/L for detection of H2 O2 . It could be utilized for the determination of H2 O2 in milk samples. © 2022, Youke Publishing Co.,Ltd. All rights reserved.
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关 键 词: | 硼掺杂石墨烯 钯纳米颗粒 电化学催化 过氧化氢 |
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