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部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展
引用本文:米亚金,杨艳春,王晓宁,朱成军.部分阳离子取代优化铜锌锡硫硒薄膜太阳能电池性能研究进展[J].发光学报,2022(2):255-267.
作者姓名:米亚金  杨艳春  王晓宁  朱成军
作者单位:1. 内蒙古师范大学物理与电子信息学院内蒙古自治区功能材料物理与化学重点实验室;2. 内蒙古自治区稀土功能和新能源储能材料工程研究中心;3. 内蒙古大学物理科学与技术学院
基金项目:国家自然科学基金(61804085,62164010,62064010);内蒙古自治区自然科学基金(2020LH6008);中央引导地方科技发展资金(2020ZY0009);中国博士后科学基金(2019M653806XB);内蒙古师范大学校级研究生科研创新基金(CXJJS21130);内蒙古师范大学校级大学生创新创业训练计划(XCY-2140)资助项目。
摘    要:作为无机化合物薄膜太阳能电池中具有代表性的一类电池,铜锌锡硫硒(Cu2ZnSn(S,Se)4,简称CZTSSe)薄膜太阳能电池因其组成元素地壳含量丰富、低毒等优点受到广泛关注.目前,吸收层的高缺陷密度和器件的低开路电压被认为是限制该类电池效率的两个关键因素.为了突破这两大困境,科研人员发展了阳离子取代方法,即通过引入其...

关 键 词:薄膜太阳能电池  铜锌锡硫硒  阳离子取代

Research Progress on Optimizing Performance of Cu2ZnSn(S,Se)4 Thin-film Solar Cells by Partial Cation Substitutions
MI Ya-jin,YANG Yan-chun,WANG Xiao-ning,ZHU Cheng-jun.Research Progress on Optimizing Performance of Cu2ZnSn(S,Se)4 Thin-film Solar Cells by Partial Cation Substitutions[J].Chinese Journal of Luminescence,2022(2):255-267.
Authors:MI Ya-jin  YANG Yan-chun  WANG Xiao-ning  ZHU Cheng-jun
Institution:(Inner Mongolian Key Laboratory for Physics and Chemistry of Functional Materials, School of Physics and Electronic Information, Inner Mongolia Normal University, Hohhot 010020, China;Inner Mongolia Autonomous Region Engineering Research Center for Rare Earth Functions and New Energy Storage Materials, Hohhot 010020, China;School of Physics Science and Technology, Inner Mongolia University, Hohhot 010021, China)
Abstract:As a representative of inorganic thin film solar cells,Cu2ZnSn(S,Se)4(CZTSSe)thin film solar cells have attracted much extensive attention,since the constituent elements are rich in earth,low toxic,etc.At present,high defect density of the absorber layer and low open circuit voltage of device are both considered as two key factors limiting the efficiency of device.In order to break though the two difficulties,the researchers developed the substitutions of Cu+/Zn2+/Sn4+by another cation.This can optimize the film properties of the harmful defects,crystal structure,and band structure,improving the performance of devices.Here,we classify by equivalent and inequivalent cation substitutions to elaborate current research development of CZTSSe thin film solar cells by cation substitution,and summarize their advantage and disadvantage in optimizing performance of devices.
Keywords:thin film solar cell  Cu2ZnSn(S  Se)4  cation substitutions
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