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Cerium(IV)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure
Authors:Yi Xiao-Yi  Y Sung Herman H  Williams Ian D  Leung Wa-Hung
Institution:Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
Abstract:Interaction of Ce(L(OEt))(2)(NO(3))(2)] (L(OEt)(-) = Co(eta(5)-C(5)H(5)){P(O)(OEt)(2)}(3)](-)) with (NH(4))(6)Mo(7)O(24)] in water affords the cerium(iv)-containing oxomolybdenum cluster H(4)(CeL(OEt))(6)Mo(9)O(38)], which exhibits a unique Ce(6)Mo(9)O(38) core structure.
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