Cerium(IV)-containing oxomolybdenum cluster with a unique Ce6Mo9O38 core structure |
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Authors: | Yi Xiao-Yi Y Sung Herman H Williams Ian D Leung Wa-Hung |
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Institution: | Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China. |
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Abstract: | Interaction of Ce(L(OEt))(2)(NO(3))(2)] (L(OEt)(-) = Co(eta(5)-C(5)H(5)){P(O)(OEt)(2)}(3)](-)) with (NH(4))(6)Mo(7)O(24)] in water affords the cerium(iv)-containing oxomolybdenum cluster H(4)(CeL(OEt))(6)Mo(9)O(38)], which exhibits a unique Ce(6)Mo(9)O(38) core structure. |
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