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Molecular structure of carbonyl bromide as studied by gas electron diffraction |
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| Authors: | Munetaka Nakata Tsutomu Fukuyama CJ Wilkins Kozo Kuchitsu |
| Institution: | Department of Chemistry, Faculty of Science, The University of Tokyo, Bunkyo-ku, Tokyo 113 Japan |
| Abstract: | The molecular structure of COBr2 has been determined as follows by an analysis of electron diffraction intensity: rg(CO) = 1.178 ± 0.009 Å, rg(C-Br) = 1.923 ± 0.005 Å and θ°α(Br-C-Br) = 112.3 ± 0.4°. The uncertainties represent estimated limits of error. The observed systematic trends in the bond lengths and bond angles in carbonyl and thiocarbonyl halides are discussed. |
| Keywords: | Present address: The National Institute for Environmental Studies Yatabe Tsukuba-gun Ibaraki 305 Japan |
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