Etude par resonance magnetique nucleaire de composes organiques contenant des chalcogenes: Partie IV. Le disulfure de diphényle et ses analogues sélénié et telluré |
| |
Authors: | Gabriel Llabres Marcel Baiwir Léon Christiaens Jean-Louis Piette |
| |
Institution: | Institut de Physique B5 Belgique;Laboratoire de Chimie organique hétérocyclique B6, Université de Liège au Sart Tilman, B-4000 LiègeBelgique |
| |
Abstract: | NMR measurements (1H, 13C, 77Se) of diphenyl dichalcogenides are reported. They confirm the molecular conformation deduced from other physical experiments. Steric inhibitions are responsible for the conformation in the Te compound, while, in the S and Se compounds, the heteroatom lone pairs interact to some extent with the π systems of the rings.More fundamental discussions of the measured parameters are made, including the somewhat controversial existence of the title compounds in solution. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|