An investigation of the molecular structure of cycloheptanone by gas phase electron diffraction |
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| Authors: | J. Dillen H.J. Geise |
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| Affiliation: | University of Antwerp (U.I.A.), Department of Chemistry, Universiteitsplein 1, B-2610 WilrijkBelgium |
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| Abstract: | The electron diffraction data of cycloheptanone, collected at 371 K, can be explained using a model of partial pseudorotation, with the symmetrical twist—chair as the mean structure. Therg, rα-structure is characterized by r(C-C) = 1.536 Å, r(C=O) = 1.219 Å, r(C-H) = 1.124 Å, xxxCC(sp2)C = 117.3°, xxx(CCC = 115.5° and xxx(HCH = 103.2°. Approximate values for the constants of the pseudorotation potential are included. |
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